Journal of Agricultural and Food Chemistry p. 498 - 502 (1995)
Update date:2022-08-23
Topics:
Palmer, Christopher J.
Casida, John E.
1,3-Oxathianes with suitable 2- and 5-substituents are highly potent insecticides.In some cases 1,3-oxathiane 3-oxides and 1,3-oxathiane 3,3-dioxides derived by m-chloroperoxybenzoic acid oxidation of the 1,3-oxathianes are even more effective.Housefly LD50s for trans-5(e)-tert-butyl-2(e)-(4-ethynylphenyl)-1,3-oxathiane 3,3-dioxide are 0.3 and 0.03 μg/g alone and with piperonyl butoxide, respectively.It is the most insecticidal analogue in the oxathiane series and approaches the potency of (1R)-cis-permethrin.Keywords: Oxathianes; dioxanes; dithianes; trioxabicyclooctanes; insecticide
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