Tetrahedron Letters p. 4723 - 4726 (1994)
Update date:2022-08-17
Topics:
Clennan, Edward L.
Wang, Dongyi
Zhang, Houwen
Clifton, Christine H.
Photooxidations of a series of 9 disulfides reveal that the thiosulfinate/thiosulfonate product ratios can be dramatically influenced by the nature of the solvent.The unique ability of methanol to influence this ratio is attributed to nucleophilic addition to a thiopersulfoxide intermediate.
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