Photooxidations of Sulfenic Acid Derivatives 2. A Remarkable Solvent Effect on the Reactions of Singlet Oxygen with Disulfides.

DOI: 10.1016/S0040-4039(00)76951-6

Source and publish data:

Tetrahedron Letters p. 4723 - 4726 (1994)

Update date:2022-08-17

Topics:

Authors:

Clennan, Edward L.

Wang, Dongyi

Zhang, Houwen

Clifton, Christine H.

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Article abstract of DOI:10.1016/S0040-4039(00)76951-6

Photooxidations of a series of 9 disulfides reveal that the thiosulfinate/thiosulfonate product ratios can be dramatically influenced by the nature of the solvent.The unique ability of methanol to influence this ratio is attributed to nucleophilic addition to a thiopersulfoxide intermediate.

Full text of DOI:10.1016/S0040-4039(00)76951-6

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