Catalytic Conversion of Allylic Esters to Corresponding Allylic Silanes with Hexamethyldisilane and Palladium(0) or Rhodium(I) Complexes

DOI: 10.1246/bcsj.57.607

Source and publish data:

Bulletin of the Chemical Society of Japan p. 607 - 608 (1984)

Update date:2022-08-16

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Authors:

Urata, Hisao

Suzuki, Hiroharu

Moro-oka, Yoshihiko

Ikawa, Tsuneo

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Article abstract of DOI:10.1246/bcsj.57.607

Treatment of allylic esters (R¹CH=CR²CH₂OCOR³:R¹=H,Ar;R²=H, alkyl; and R³=Me,Ph) with hexamethyldisilane in the presence of catalytic amounts of PdL₄ (L=PPh3 or P(OPh)3) or RhCl(PPh3)3 gives the corresponding allylic silanes in the excellent yield.

Full text of DOI:10.1246/bcsj.57.607

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