Tetrahedron Letters p. 5445 - 5448 (1993)
Update date:2022-08-29
Topics:
Parrain, Jean-Luc
Beaudet, Isabelle
Duchene, Alain
Watrelot, Sandrine
Quintard, Jean-Paul
The easily prepared and stored E-1-tributylstannyl-3,3-diethoxy-prop-1-ene 1E reacts with acyl chlorides in DMF in the presence of PdCl2(MeCN)2 to give the expected 1,4-ketoacetals (E isomers).Similarly cross coupling of 1E with tosyl chloride performed i
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