Boron trifluoride etherate - An effective catalyst of 1,3-phosphorotropic migration in C = N-C triad

DOI: 10.1016/S0040-4039(00)92344-X

Source and publish data:

Tetrahedron Letters p. 691 - 694 (1992)

Update date:2022-08-16

Topics: Migration Coordination Activation Release

Authors:

Onys'ko Onys'ko

Kim Kim

Kiseleva

Sinitsa Sinitsa

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Article abstract of DOI:10.1016/S0040-4039(00)92344-X

A facile BF₃ · Et₂O promoted 1,3-transfer of a diphenylphosphinoyl group in a 2-azaallylic systsem has been found. The isomerization was shown to proceed by an intramolecular mechanism in the complex formed with participation of a phosphorylated imine P = O group.

Full text of DOI:10.1016/S0040-4039(00)92344-X

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Article Doi

Boron trifluoride etherate - An effective catalyst of 1,3-phosphorotropic migration in C = N-C triad

DOI: 10.1016/S0040-4039(00)92344-X

Source and publish data:

Authors:

Article abstract of DOI:10.1016/S0040-4039(00)92344-X

Full text of DOI:10.1016/S0040-4039(00)92344-X

Products guided by the article

R&D Labs maybe for 140157-02-4

Relevant to this article

Quadruple domino organocatalysis: An asymmetric aza-Michael/Michael/ Michael/Aldol reaction sequence leading to tetracyclic indole structures with six stereocenters

Low molecular weight proteins as carriers for renal drug targeting. Preparation of drug-protein conjugates and drug-spacer derivatives and their catabolism in renal cortex homogenates and lysosomal lysates

Sequential Csp3-H arylation and olefination: Total synthesis of the proposed structure of pipercyclobutanamide a

Aryne 1,2,3-Trifunctionalization with Aryl Allyl Sulfoxides

Trifunctional photoinitiators based on a triazine skeleton for visible light source and UV LED induced polymerizations

New catalytic system Cu(OAc)2-2,4-lutidine-ZnCl2 for olefin cyclopropanation with methyl diazoacetate

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New catalytic system Cu(OAc)₂-2,4-lutidine-ZnCl₂ for olefin cyclopropanation with methyl diazoacetate