(triphenylphosphine)dichlororuthenium(II): an Enantioselective Catalyst for the Hydrogenation of Diketones

DOI: 10.1039/c39910001675

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1675 - 1677 (1991)

Update date:2022-08-11

Topics:

Authors:

Mezzetti, Antonio

Consiglio, Giambattista

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39910001675

The novel species > 1 and 2-BH4)(PPh3)<(S)-biphemp>> 3 have been synthesized; 1 has a labile triphenylphosphine ligand and is a very active and enantioselective catalyst for the mono- or bis-hydrogenation of pentane-2,4-dione.

Full text of DOI:10.1039/c39910001675

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[RuCl₂(PPh₃)((S)-2,2'-bis(diphenylphosphino)-6,6'-dimethylbiphenyl)]

Cas No:140482-33-3

R&D Labs maybe for 140482-33-3

Nanjing Duly Biotech Co., Ltd

website:http://www.dulynet.com/

Contact:025-84699383 -8003

Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
SHIJIAZHUANG AGERUO-BIOTECH CO.LTD

Contact:+86-130-2866-6699

Address:Huaian east Road 158
Shijiazhuang Haotian Chemical Co., Ltd.

Contact:86-311-85044374

Address:293 Donggang Road
Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601
Simagchem Corporation

website:http://www.simagchem.com

Contact:+86-592-2680277

Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China

Relevant to this article

Tandem selective reduction of nitroarenes catalyzed by palladium nanoclusters

Doi:10.1039/c9gc03957k
(2020)
P₂Et Phosphazene: A Mild, Functional Group Tolerant Base for Soluble, Room Temperature Pd-Catalyzed C-N, C-O, and C-C Cross-Coupling Reactions

Doi:10.1021/acs.orglett.5b01648
(2015)
Synthesis of a Spirocyclic Indoline Lactone

Doi:10.1021/jo0499569
(2004)
Revision of absolute configuration of enantiomeric (methylenecyclopropyl)carbinols obtained from (R)-(-)- and (S)-(+)-epichlorohydrin and methylenetriphenylphosphorane. Implications for reaction mechanism and improved synthesis of antiviral methylenecyclo

Doi:10.1021/jo010511j
(2002)
Sugar-based hydrophilic polyurethanes and polyureas

Doi:10.1002/pola.24621
(2011)
An expeditious study of the nature of halogen(s) at α-positions in carbonyl compounds

Doi:10.1080/00397919208021670
(1992)

Article Doi