Solvent effects on the solvolyses of N-benzoyl-arenesulfonimidoyl chlorides

Article abstract of DOI:10.1080/10426500108040254

Rates of solvolyses of N-benzoyl-arenesulfonimidoyl chlorides have been studied in different compositions of aqueous organic solvents and analysed in terms of the mol fraction of organic solvent, the dielectric constant, the Kirkwood function, the polarisibility, some E^N_T values, a multiparameter equation and the Grunwald-Winstein equation. All these criteria were consistent with a concerted bimolecular S_N2 mechanism of solvolysis.

Full text of DOI:10.1080/10426500108040254

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Phosphorus, Sulfur, and Silicon
and the Related Elements
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SOLVENT EFFECTS ON THE
SOLVOLYSES OF N-BENZOYL-
ARENESULFONIMIDOYL
CHLORIDES
Halil Kutuk a c & John G Tilleit b
a Department of Biological and Chemical Sciences,
University of Essex, Wivenhoe Park, Colchester, CO4
3SQ, U.K
b Centre for Lifelong Laming University of Essex
Colchester Essex, CO4 3SA, UK
c Ondokuz Mayis University, Faculty of Arts and
Sciences, Chemistry Department, 55139, Kurupelit,
Samsun, Turkey
Available online: 04 Oct 2006
To cite this article: Halil Kutuk & John G Tilleit (2001): SOLVENT EFFECTS ON THE
SOLVOLYSES OF N-BENZOYL-ARENESULFONIMIDOYL CHLORIDES, Phosphorus, Sulfur, and
Silicon and the Related Elements, 175:1, 35-47
To link to this article: http://dx.doi.org/10.1080/10426500108040254
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