The reactions of phenyldimethylsilyllithium with nitriles

DOI: 10.1016/0022-328X(96)06220-1

Source and publish data:

Journal of Organometallic Chemistry p. 121 - 124 (1996)

Update date:2022-08-05

Topics:

Authors:

Fleming, Ian

Solay, Monica

Stolwijk, Frederik

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(96)06220-1

Phenyldimethylsilyllithium reacts with nitriles by several substantially different pathways depending upon the structure of the nitrile. The products include the acylsilane 2 from pivalonitrile (1), cumylsilane 5 from 2-phenylisobutyronitrile (4), the α-anion from phenylacetonitrile (9), and a mixture of benzil (15) and 2,4,5-triphenylimidazole (17) from benzonitrile (13).

Full text of DOI:10.1016/0022-328X(96)06220-1

Products guided by the article

Product name:phenylacetonitrile d-1

Cas No:14072-73-2

R&D Labs maybe for 14072-73-2

Golden Union Agrochemical Import and Export Co., Ltd.

Contact:86-755-23910527

Address:Room 1106, Tower 3A, Excellence Century Center, Futian District, Shenzhen, China
Xiamen Kaijia Imp & Exp Co., Ltd.

Contact:86-592-5101177

Address:Room406 Luhui Building No. 65 Haitian Road Huli Xiamen,China.
Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.

Contact:+86-750-2881198

Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
ChangZhou Mascotchem. Co.,Ltd.

website:http://www.mascotchem.com

Contact:86-519-85010339

Address:B-802,XingBei Building,391#,Tongjiang Middle Road New District,Changzhou,JS,China
Jining tiansheng chemical co.,ltd.

Contact:+86-537-5158722

Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA

Relevant to this article

Synthesis and Characterization of Fluorescent 4,6-Disubstituted-3-cyano-2-methylpyridines

Doi:10.1039/P29920000201
(1992)
Lipase-catalyzed asymmetric synthesis of (R)- and (S)-4-tert-butyldimethylsilyloxy-2,6,6-trimethyl-2-cyclohexenone and their dihydro derivatives

Doi:10.1016/0957-4166(95)00159-M
(1995)
Birch Reductive Alkylation of Methyl m-(Hydroxymethyl)benzoate Derivatives and the Behavior of o- and p-(Hydroxymethyl)benzoates under Reductive Alkylation Conditions

Doi:10.1021/jo301872n
(2013)
Synthesis and Radical Polymerization of Itaconates Containing an Adamantyl Ester Group

Doi:10.1246/bcsj.65.846
(1992)
Synthesis of (5R,6R,7S)-6-iodo-1,5,6,7-tetrahydro-4,1-benzoxazonin-3(2H)-ones

Doi:10.1134/S1070428014100121
()
Investigation of radiopharmaceuticals for pancreatic imaging: Accumulation of amines in the pancreas

Doi:10.1248/cpb.40.161
(1992)

Article Doi