The reactions of phenyldimethylsilyllithium with nitriles

DOI: 10.1016/0022-328X(96)06220-1

Source and publish data:

Journal of Organometallic Chemistry p. 121 - 124 (1996)

Update date:2022-08-05

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Authors:

Fleming, Ian

Solay, Monica

Stolwijk, Frederik

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Article abstract of DOI:10.1016/0022-328X(96)06220-1

Phenyldimethylsilyllithium reacts with nitriles by several substantially different pathways depending upon the structure of the nitrile. The products include the acylsilane 2 from pivalonitrile (1), cumylsilane 5 from 2-phenylisobutyronitrile (4), the α-anion from phenylacetonitrile (9), and a mixture of benzil (15) and 2,4,5-triphenylimidazole (17) from benzonitrile (13).

Full text of DOI:10.1016/0022-328X(96)06220-1

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