Tetrahedron Letters p. 2749 - 2752 (1997)
Update date:2022-08-28
Topics:
Simoni, Daniele
Invidiata, Francesco Paolo
Manfredini, Stefano
Ferroni, Roberto
Lampronti, Ilaria
Roberti, Marinella
Pollini, Gian Piero
Tetramethylguanidine-catalyzed addition of primary nitroalkanes to aldehydes and alicylic ketones constitutes a practical means to perform the nitro-aldol reaction (Henry reaction). The very mild conditions employed, together with the short reaction times, make the procedure tolerant of a range of functionalities and highly versatile for the synthesis of a variety of 2-nitroalkenols.
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