Journal of Organic Chemistry p. 1729 - 1740 (1987)
Update date:2022-08-11
Topics:
D'Souza, Valerian T.
Nanjundiah, Raghunath
Baeza, H. Jaime
Szmant, H. Harry
The rate of oxygen consumption and the product distribution in the TOCO reaction under various experimental conditions are investigated and a self-consistent mechanism for the reaction under nonradical-inducing conditions is proposed that takes into consideration the observed structural and catalytic effects.Some interesting similarities between hydrogen bromide-olefin and thiol-olefin systems are discussed.
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