Preparation of Alkylnickel(II)-Phosphine Complexes by Reactions of Ni(acac)2 with Alkylaluminums in the Presence of Tertiary Phosphine

Article abstract of DOI:10.1246/bcsj.55.325

Four new alkylnickel(II)-phosphine complexes, NiR2(PR'3)2 (R=CH3, C2H5; PR'3=triethylphosphine (PEt3), tributylphosphine (PBu3), 1,2-bis(diphenylphosphino)ethane(dpe)) and Ni(CH3)(acac)(PEtPh2) (PEtPh2=ethyldiphenylphosphine), have been prepared by reacti