Bis1N'>gold(III) Complexes. Crystal and Molecular Structure of Bis1N'>gold(III) Tetrachloroaurate

DOI: 10.1039/DT9840000557

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 557 - 562 (1984)

Update date:2022-08-11

Topics:

Authors:

Vicente, Jose

Chicote, Maria-Teresa

Bermudez, Maria-Dolores

Solans, Xavier

Font-Altaba, Manuel

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Article abstract of DOI:10.1039/DT9840000557

The reaction between and gave the gold(III) complex which reacts with AgClO4 to form ClO4.Addition of X (X=Cl), NaX (X=Br), or KX (X=I, CN or O2CMe), to the cationic complex leads to the corresponding neutral complexes .Reaction of ClO4 with -, leads to .By reacting the neutral acetato-complex with ClO4 (Hpy=pyridinium), ClO4 is prepared.The crystal structure of has been determined and shows that the cation has a square-planar co-ordination with two cis-nitrogen and the two cis-carbon atoms bonded to gold.

Full text of DOI:10.1039/DT9840000557

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