SYNTHESIS OF α-METHYLENECYCLOPENTANONES VIA SILICON-DIRECTED NAZAROV REACTION OF α-TRIMETHYLSILYLMETHYL-SUBSTITUTED DIVINYL KETONES

DOI: 10.1016/S0040-4039(00)92672-8

Source and publish data:

Tetrahedron Letters p. 3495 - 3498 (1992)

Update date:2022-08-25

Topics:

Authors:

Kang, Kyung-Tae

Kim, Soung Sin

Lee, Jae Chul

U, Jong Sun

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Article abstract of DOI:10.1016/S0040-4039(00)92672-8

Reactions of α-trimethylsilylmethyl-substituted divinyl ketones with FeCl3 gave α-methylene-cyclopentanones.Thienyl and N-methylpyrrolyl (α-trimethylsilylmethyl)vinyl ketones also underwent cyclization to afford the corresponding α-methylenecyclopentanone

Full text of DOI:10.1016/S0040-4039(00)92672-8

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