Photochemically induced [2 + 2] cycloaddition of a silacyclopentadiene with carbon disulfide

DOI: 10.1016/0040-4039(92)88088-M

Source and publish data:

Tetrahedron Letters p. 4013 - 4016 (1992)

Update date:2022-08-16

Topics:

Authors:

Nakadaira, Yasuhiro

Ohkura, Yoshiyuki

Kyushin, Soichiro

Ohashi, Mamoru

Sakurai, Hideki

Ueno, Kimitoshi

Kanouchi, Seiichi

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Article abstract of DOI:10.1016/0040-4039(92)88088-M

A silacyclopentadiene (silole) undergoes photo-induced [2+2] cycloaddition with CS₂ to afford the corresponding β-dithiolactones. The electron transfer from singlet excited state of the silole to CS₂ is shown to play an important role in the cycloaddition reaction.

Full text of DOI:10.1016/0040-4039(92)88088-M

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