Tetrahedron Asymmetry p. 2271 - 2278 (1997)
Update date:2022-08-16
Topics:
Manickam
Sundararajan
A C2-symmetric chiral amino diol (1R,5R)-3-aza-3-benzyl-1,5-diphenyl pentan-1,5-diol [(R,R)-I] has been synthesised by a modified procedure. The heterobimetallic catalyst [I2-AI-Li] obtained by reaction of the amino diol [(R,R)-I] with LiAlH4, promotes asymmetric Michael addition of malonic esters and thiophenols to α,β-unsaturated compounds with high enantiomeric excess.
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