Tetrahedron Asymmetry p. 1783 - 1788 (1996)
Update date:2022-08-18
Topics:
Solladie-Cavallo, Arlette
Diep-Vohuule, Anh
Sunjic, Vitomir
Vinkovic, Vladimir
Pure trans-(R,R)-diaryl-epoxides are obtained in two steps and under aprotic conditions using Eliel's oxathiane as the chiral auxiliary. The enantiomeric excesses, determined by chiral HPLC, are 97.9% to 99.9% and the oxathiane is recovered in 78% to 92% yield and may thus be re-used.
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(1977)
