Tetrahedron Asymmetry p. 3995 - 3998 (1997)
Update date:2022-08-18
Topics:
Adam, Waldemar
Zhao, Cong-Gui
The new optically active C2-symmetric ketones 3a (from mannitol) and 3b (from TADDOL) were prepared and the in-situ-generated dioxiranes (with Caroate(TM) as peroxide source) were shown to serve as effective oxidants for the asymmetric epoxidation (ee values up to 81%) of prochiral trans and trisubstituted olefins.
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