Tetrahedron Letters p. 4427 - 4430 (1996)
Update date:2022-08-16
Topics:
Sammakia, Tarek
Hurley, T. Brian
Sammond, Douglas M.
Smith, Randall S.
Sobolov, Susan B.
Oeschger, Thomas R.
The dihydroxylation of olefins using AD-mix or OsO4/K3Fe(CN)6 in the presence of sulfides has been examined as has the rate of oxidation of various classes of sulfides. The selectivity of olefin oxidation in preference to sulfur oxidation depends on the nature of the sulfur moiety, and can be problematic for certain classes of substrates.
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