Synthesis and rearrangement of (Z)-allylic trichloroacetimidates

DOI: 10.1016/S0040-4039(99)00626-7

Source and publish data:

Tetrahedron Letters p. 3735 - 3736 (1999)

Update date:2022-08-10

Topics:

Authors:

Martin, Catherine

Bortolussi, Michel

Bloch, Robert

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Article abstract of DOI:10.1016/S0040-4039(99)00626-7

An efficient synthesis of (Z)-allylic trichloroacetimidates starting from lactol 1 is described. Thermal [3,3] rearrangement of these imidates occurred with excellent chirality transfer to give allylic amides.

Full text of DOI:10.1016/S0040-4039(99)00626-7

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