Journal of Organic Chemistry p. 4511 - 4512 (1993)
Update date:2022-08-11
Topics:
Kim, Yong Hae
Park, Doo Han
Byun, Il Suk
Yoon, I. K.
Park, C. S.
The highly stereocontrolled enantioselective reduction of ketones in the presence of catalytic amounts of new chiral (S)-β-amino alcohols 1 and 2 with borane in THF at -78 deg C proceeds in high chemical and optical yields; secondary alcohols with the R-configuration are obtained in the presence of 1b, but secondary alcohols with the S-configuration are obtained in the presence of 2a
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