Journal of the Chemical Society. Chemical communications p. 1359 - 1361 (1992)
Update date:2022-08-16
Topics:
Younger, Charles G.
Bell, Russell A.
Photolysis of the monocyclic aryl azide 3-acetamido-4-trifluoroacetamidophenyl azide, 1a, furnished a long-lived, trapable azirine intermediate, 7, which was in equilibrium with the initially formed nitrene and subsequently rearranged to the didehydroazepine intermediate 5; the data presented demonstrate that mono- and bi-cyclic aryl azides follow the same chemistry, with the substituents controlling the observed product distribution.
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