Organometallics p. 3015 - 3018 (1993)
Update date:2022-08-04
Topics:
Reifenberg, Gerald H.
Considine, William J.
The reactions of stannane with a variety of organic substrates have been studied. Benzaldehyde, acetone, nitrobenzene, and 2-nitropropane are reduced to benzyl alcohol, isopropyl alcohol, aniline, and isopropylamine, respectively. With boron trifluoride etherate and benzyl chloride, stannane undergoes halogen-hydrogen exchange, while with isopropylamine and acetic acid, it is decomposed catalytically into its elements. Tetrakis(2-cyanoethyl)tin is formed by the addition of stannane to acrylonitrile. Stannane did not react with the following: (a) ethyl acetate, (b) methyl acrylate, (c) aniline, (d) triethylamine, (e) dimethylacetamide, and (f) N-ethylacetamide. The results obtained with stannane are for the most part analogous to those reported for the corresponding organotin hydrides.
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Doi:10.1134/S1070363213070116
(2013)Doi:10.1002/cmdc.201200561
(2013)Doi:10.1080/10426507.2012.740695
(2013)Doi:10.1021/ja405588x
(2013)Doi:10.1016/0040-4039(96)00918-5
(1996)Doi:10.1016/S0040-4020(01)90165-6
(1993)
