Bulletin of the Chemical Society of Japan p. 1761 - 1766 (1987)
Update date:2022-08-16
Topics:
Minowa, Nobuto
Hirayama, Masao
Fukatsu, Shunzo
(S)-(+)-Phosphinothricin was prepared in good optical yield by th Michael addition of chiral glycine Schiff base derived from (S)-2-hydroxy-3-pinanone to vinyl phosphorus compound. (R)-(-)-Phosphinothricin, an enantiomeric isomer, can also be prepared from the same chiral glycine Schiff base by choosing suitable reaction temperature.
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