Tetrahedron Letters p. 5315 - 5318 (1984)
Update date:2022-08-26
Topics:
Shinkai, Seiji
Mori, Seiichi
Tsubaki, Takayuki
Sone, Takaaki,
Manabe, Osamu
4-Sulfonate derivatives of calix<6>arene and O-n-hexylcalix<6>arene (1a and 1b, respectively) were synthesized.Measurements using fluorescence and absorption spectral probes indicated that the cavity of calix<6>arene can accept a naphthalene molecule but not pyrene molecule and that (1b) has a hydrophobic cavity constructed from the aggregate of the hexyl groups while (1a) provides a reaction field apparently more polar than water.This is the first example for water-soluble host molecules derived from calix<6>arene.
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