New Ruthenium(II) Complexes of α,α'-Diimines. Synthesis, Electrochemical and Optical Spectral Properties of Mononuclear Complexes containing Aryl(2-pyridylmethylene)amine and 2,2'-Bipyridine Ligands

DOI: 10.1039/DT9940001305

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1305 - 1310 (1994)

Update date:2022-08-11

Topics:

Authors:

Choudhury, Subrata

Deb, Alok K.

Goswami, Sreebrata

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940001305

The tris-chelated complexes, n(bipy)_3-n)>2*H2O , have been prepared based on a direct and general route.For (2+), the geometry has been assessed by 1H NMR spectroscopy.All the complexes show metal-to-ligand charge transfer (m.l.c.t.) transitions in the visible range at ca. 475 nm.Preliminary results of emission spectra are also described briefly.The metal oxidation as well as ligand reductions for the complexes have been studied electrochemically in acetonitrile using different working electrodes.It has been shown, for the mixed L-bipy complexes, that the reductions of co-ordinated L occur at comparatively lower negative potentials.The correlation between the electrochemical properties and v_c.t. (absorption) is discussed.

Full text of DOI:10.1039/DT9940001305

View Online / Journal Homepage / Table of Contents for this issue

View Online

Products guided by the article

Product name:cis-trans-cis-Ru(2-phenylazopyridine)₂Cl₂

Cas No:146565-06-2

R&D Labs maybe for 146565-06-2

taizhou creating bio-pharm co.,ltd.

Contact:+86- 576- 88827176

Address:715 room ,unit A.junyue Building,Jiaojiang,Taizhou,Zhejiang,China
Mollt Biochem Co., Ltd(expird)

Contact:+86-21-38682181

Address:shanghai ,china
Xuzhou Tianrun Chemical Co.,Ltd

website:http://www.tianrunchem.cn

Contact:86-516-83832636

Address:fuxing road
Shandong Xiangde Biotechnology Co., Ltd

Contact:+86 -15066639877

Address:Sanba street
Shanghai Standard Biotech Co., Ltd.

Contact:+86-18502101150

Address:Room 103, Building 2nd, NO.720, Cailun Road , Pudong District, Shanghai, China

Relevant to this article

Glycerol ingrained copper: An efficient recyclable catalyst for the N-arylation of amines with aryl halides

Doi:10.1016/j.tetlet.2013.03.062
(2013)
Extraction of technetium(VII) by calix[4]arene tetraketones and tetraesters from acidic and basic media

Doi:10.1023/B:RUCB.0000024840.85337.48
(2004)
Doi:10.1021/cr60060a007
(1936)
Doi:10.1021/ja01864a037
(1940)
Gas-phase epoxidation of 3,3,3-trifluoropropylene over Au/CuTiO₂ catalysts with N₂O as the oxidant

Doi:10.1016/j.jcat.2014.01.015
(2014)
Dinuclear ru-aqua complexes for selective epoxidation catalysis based on supramolecular substrate orientation effects

Doi:10.1002/chem.201304699
(2014)

Article Doi