The reaction of enaminones with grignard reagents: Synthesis of α,β- unsaturated ketones

Article abstract of DOI:10.1080/00397919808007005

Enaminones in toluene react with Grignard reagents in tetrahydrofuran at 0-25 °C, to give selectively and with high yields the corresponding α,β- unsaturated ketones.

Full text of DOI:10.1080/00397919808007005

This article was downloaded by: [Georgia Tech Library]
On: 16 November 2014, At: 07:06
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
The Reaction of Enaminones
with Grignard Reagents:
Synthesis of α,β-Unsaturated
Ketones
a
a
a
C. Fontenas , H. Aït-Haddou , E. Bejan & G. G.
a
A. Balavoine
a
Laboratoire de Chimie de Coordination, CNRS 205
Route de Narbonne , F-31077, Toulouse, Cedex,
France
Published online: 20 Aug 2006.
To cite this article: C. Fontenas , H. Aït-Haddou , E. Bejan & G. G. A. Balavoine
(1998) The Reaction of Enaminones with Grignard Reagents: Synthesis of α,β-
Unsaturated Ketones, Synthetic Communications: An International Journal for
Rapid Communication of Synthetic Organic Chemistry, 28:10, 1743-1753, DOI:
10.1080/00397919808007005
To link to this article: http://dx.doi.org/10.1080/00397919808007005
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.
However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views

expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions