Journal of the Chemical Society - Faraday Transactions p. 3129 - 3136 (1991)
Update date:2022-08-25
Topics:
O'Connell, Aidan B.
Chandra, Harish
Mishra, Shuddhodan P.
Hasegawa, Akinori
Symons, Martyn C. R.
Irradiation of the pure title compounds and a range of dilute solid solutions produces a range of matrix-isolated radicals, identified by their EPR spectra.These include electron-loss centres, HN.CN and (Me2N.CN)+, and electron capture centres HNC(H)N.- and Me2N..The former is a tautomer of the parent anion and the latter is formed by loss of CN-.In aqueous alkali glasses, the radical anion .N2CO3- is thought to be formed by addition of O.- to CN22-.
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