LEWIS ACID CATALYSED PINACOL REARRANGEMENT - A SHORT SYNTHESIS OF KARAHANAENONE

DOI: 10.1246/cl.1982.1537

Source and publish data:

Chemistry Letters p. 1537 - 1538 (1982)

Update date:2022-08-23

Topics:

Authors:

Bhushan, Vidya

Chandrasekaran, Srinivasan

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Article abstract of DOI:10.1246/cl.1982.1537

The pinacolic coupling reaction has been effectively used to prepare the unsymmetrical pinacol 2 and this key intermediate underwent a smooth ring enlargement to the monoterpene karahanaenone 3, an odoriferous constituent of Japanese hop and Cypress oil.

Full text of DOI:10.1246/cl.1982.1537

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