Synthesis of thiiranes through direct sulfur transfer to cycloalkenes in the thermolysis of a thiophene endoperoxide

DOI: 10.1039/CC9960000177

Source and publish data:

Chemical Communications p. 177 - 178 (1996)

Update date:2022-08-04

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Authors:

Adam, Waldemar

Weinkoetz, Stephan

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Article abstract of DOI:10.1039/CC9960000177

Thiophene endoperoxide 2, which was prepared by photo-oxygenation of thiophene 1, transfers a sulfur atom to form thiiranes when thermolysed in the presence of cycloalkenes, an unexpectedly efficient process which can be catalysed by the cobalt-tetraphenylporphine complex.

Full text of DOI:10.1039/CC9960000177

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