Product analysis in the iodine(III)-promoted oxidation of carbohydrate-derived cyclic enol ethers: A mechanistic study

DOI: 10.1002/jlac.199719971015

Source and publish data:

Liebigs Annalen p. 2125 - 2132 (1997)

Update date:2022-08-30

Topics:

Authors:

Harders, Jan

Garming, Alfons

Jung, Alexander

Kaiser, Volker

Monenschein, Holger

Ries, Monika

Rose, Lars

Schoening, Kai-Uwe

Weber, Thomas

Kirschning, Andreas

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Article abstract of DOI:10.1002/jlac.199719971015

A study on the mechanism of the well-documented hypervalent iodine-mediated allylic oxidation of glycals leading to 2,3-dihydro-4H-pyran-4-ones is presented. Notable features are the isolation of ring-contracted by-products 6 and 7, which are produced upo

Full text of DOI:10.1002/jlac.199719971015

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Product name:(-)-(2R,3S)-3-(Benzyloxy)-2-<(benzyloxy)methyl>-2,3-dihydro-4H-pyran-4-one

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