TEMPERATURE DEPENDENCE OF ACTIVATION VOLUME FOR ACETOLYSIS OF 2-ARYL-2-METHYLPROPYL TOSYLATES

DOI: 10.1246/cl.1980.1533

Source and publish data:

Chemistry Letters p. 1533 - 1536 (1980)

Update date:2022-08-10

Topics:

Authors:

Sera, Akira

Yamada, Hiroaki

Masaki, Hitoshi

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Article abstract of DOI:10.1246/cl.1980.1533

The activation volume of the acetolysis of the title compounds was found to have an unexpectedly large temperature dependence.The activation volume-temperature profile of a steep concave was observed which was responsible for the previously reported anomaly of the substituent dependence of the activation volume.

Full text of DOI:10.1246/cl.1980.1533

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