Isolation of ?-Alkyl-iron(III) or Carbene-iron(II) Complexes from Reduction of Polyhalogenated Compounds by Iron(II)-porphyrins: the Particular Case of Halothane CF3CHClBr

DOI: 10.1039/c39820000638

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 638 - 639 (1982)

Update date:2022-08-29

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Authors:

Mansuy, Daniel

Battioni, Jean-Paul

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Article abstract of DOI:10.1039/c39820000638

Fe^II(TPP) (TPP = tetraphenylporphyrin) in the presence of an excess of sodium dithionite, reacts with CF3CCl3 and halothane CF3CHClBr, leading respectively to the carbene Fe^II (TPP)(CClCF3) and ?-alkyl-Fe^III(TPP)(CHClCF3) complexes, the latter being the first isolated ?-alkyl-Fe^III(porphyrin) complex involving a halogen substituent on the carbon bound to iron.

Full text of DOI:10.1039/c39820000638

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