Tetrahedron Letters p. 3925 - 3928 (1995)
Update date:2022-08-28
Topics:
Stewart, Sarah K.
E- and Z-1-alkenyl iodides react with vinylboronate pinacol ester 1 under palladium(0) catalysed, Heck conditions to provide polyenylboronates in moderate yields after purification. The addition of either silver(I) or thallium(I) salts to the reaction mixture is essential. Alkenyl bromides are unreactive under identical reaction conditions.
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