Journal of Physical Chemistry p. 1505 - 1509 (1985)
Update date:2022-08-11
Topics:
Hudgens, Jeffrey W.
Dulcey, C.S.
Previously unreported bands of allyl, allyl-d5, and 2-methylallyl radicals have been detected by mass-resolved, resonance-enhanced multiphoton ionization spectrometry.Focused laser light between 480 and 535 nm induced two-photon absorptions preparing the 3s 2A1 Rydberg states of the radicals.Absorption of two additioal photons ionized the excited radicals.These electronic states of allyl and 2-methylallyl radicals lie at 40085 and 38369 cm-1, respectively.No subsequent fragmentation of the molecular ions was observed.
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