Journal of the Chemical Society. Chemical communications p. 1356 - 1358 (1988)
Update date:2022-08-24
Topics:
Humphrey, David G.
Fallon, Gary D.
Murray, Keith S.
Reaction in water of Cu(pdto)(ClO4)2 with Li(TCNQ)/TCNQ mixtures yields solid crystalline materials of formulae Cu(pdto)(TCNQ)x (x=2, 2.5, or 3) which display high electrical conductivities ; reaction of Cu(pdto)(ClO4) with Li(TCNQ) yields Cu(pdto)(TCNQ), a poor conductor which has been shown by X-ray crystallography to have a novel dimeric structure involving ?-? interaction between TCNQ units and which possesses Cu-TCNQ bonding.
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