Tetrahedron Letters p. 3065 - 3068 (1994)
Update date:2022-08-11
Topics:
Cahiez, Gerard
Figadere, Bruno
Clery, Patrick
Ketones are regioselectively converted to Mn-enolates by treatment with Mn-amides such as Ph(Me)NMnCl in THF at 20 deg C.Mn-enolates can then be regioselectively monoalkylated in good yields.The formation of di or polyalkylated products is never observed (< 1percent).
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