Journal of the Chemical Society. Chemical communications p. 1303 - 1305 (1985)
Update date:2022-08-16
Topics:
Lowther, Nicholas
Hall, C. Dennis
Acyclic phosphoranes, ArnP(OR)5-n with n=0-3 are shown to hydrolyse in neutral conditions by SN1 (P) mechanism for n=1,2, and 3 but by an SN2 (P) or addition-elimination mechanism for n=0; this is analogous to the classical SN1 vs.SN2 mechanisms observed for solvolysis reactions at tetrahedral carbon.
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