Journal of Organic Chemistry p. 1916 - 1919 (1990)
Update date:2022-08-11
Topics:
Bottaro, Jeffrey C.
Schmitt, Robert J.
Bedford, Clifford D.
Gilardi, Richard
George, Clifford
The chemistry of nitroacetylenes has been relatively unexplored owing to the lack of stable nitoacetylene derivatives.Our discovery of methods to prepare stable nitroacetylenes allows us the opportunity to investigate their chemistry.We report here on the reactions of (trialkylsilyl)nitroacetylenes in Diels-Alder, 1,3-cycloaddition reactions, and the thermolysis of nitroacetylene adducts.
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