
Journal of the American Chemical Society p. 7487 - 7493 (1980)
Update date:2022-08-16
Topics:
Nordlander, J. Eric
Haky, Jerome E.
Landino, John P.
Protoadamantene (1) reacts smoothly with neat trifluoroacetic acid at 25 deg C to give 2-adamantyl trifluoroacetate (2-OTFA) and a trace of metastable exo-4-protoadamantyl trifluoroacetate (4-OTFA), which isomerizes to 2-OTFA.The rearrangement attending a
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