Mechanism of Addition of Neat Trifluoroacetic Acid to Protoadamantene

DOI: 10.1021/ja00545a015

Source and publish data:

Journal of the American Chemical Society p. 7487 - 7493 (1980)

Update date:2022-08-16

Topics:

Authors:

Nordlander, J. Eric

Haky, Jerome E.

Landino, John P.

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Article abstract of DOI:10.1021/ja00545a015

Protoadamantene (1) reacts smoothly with neat trifluoroacetic acid at 25 deg C to give 2-adamantyl trifluoroacetate (2-OTFA) and a trace of metastable exo-4-protoadamantyl trifluoroacetate (4-OTFA), which isomerizes to 2-OTFA.The rearrangement attending a

Full text of DOI:10.1021/ja00545a015

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