Highly Stereoselective Access to 2,4- and 2,4,5-Substituted Tetrahydrofurans from α-Silylacetic Esters. A Study of Homoallylic Stereocontrol.

DOI: 10.1016/S0040-4039(00)61352-7

Source and publish data:

Tetrahedron Letters p. 8435 - 8438 (1993)

Update date:2022-08-11

Topics:

Authors:

Andrey, Olivier

Landais, Yannick

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Article abstract of DOI:10.1016/S0040-4039(00)61352-7

Cis-2,4- and cis-cis-2,4,5-substituted tetrahydrofurans have been prepared stereoselectively using electrophile-mediated cyclization of β-hydroxyhomoallylsilanes, readily available from α-silylacetic esters.

Full text of DOI:10.1016/S0040-4039(00)61352-7

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Product name:ethyl-2-(dimethylphenylsilyl)pent-4-enoate

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