Journal of the Chemical Society. Chemical communications p. 1434 - 1436 (1984)
Update date:2022-08-23
Topics:
Murakami, Yukito
Kikuchi, Jun-ichi
Imori, Toru
Akiyoshi, Kazunari
1-(N,N-Dihexadecylcarbamoylmethyl)-2-methyl-3-hydroxy-4-formyl-5-hydroxymethylpyridinium chloride (PL+2C16) undergoes a transamination reaction with L-phenylalanine in single-walled bilayer vesicles formed from two different peptide lipids (N+C5Ala2C16 and N+C5His2C16); co-ordination of copper(II) ion to the Schiff-base intermediate results in a marked rate acceleration.
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