CHIRAL HYDRIDE REAGENTS CONTAINING (R/S)-2,2'-DIHYDROXY-6,6'-DIMETHYLBIPHENYL FOR REDUCTION OF ALKYL PHENYL KETONES

DOI: 10.1246/cl.1984.899

Source and publish data:

Chemistry Letters p. 899 - 902 (1984)

Update date:2022-08-18

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Authors:

Suda, Hiroshi

Kanoh, Shigeyoshi

Umeda, Nobuhiro

Ikka, Masahiko

Motoi, Masatoshi

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Article abstract of DOI:10.1246/cl.1984.899

Chiral hydride reagents for asymmetric reduction were prepared from LiAlH4, optically pure 2,2'-dihydroxy-6,6'-dimethylbiphenyl (1), and an achiral alcohol.They showed high enantioface discrimination in the reduction of prochiral alkyl phenyl ketones.The

Full text of DOI:10.1246/cl.1984.899

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