Analytical Chemistry p. 927 - 933 (1985)
Update date:2022-08-18
Topics:
Wojciechowski
Osteryoung
The electrochemical reduction of the antibacterial agent 1,2-dibromo-2,4-dicyanobutane (DBDCB, Tektamar) at mercury electrodes in actonitrile is investigated by a variety of techniques. Reverse pulse voltammetry shows that the stoichiometry of this two-electron reduction requires the liberation of two bromide ions and an organic product of composition C//6N//2H//6 per molecule of reactant. An electroanalytical method for the determination of DBDCB based on reverse pulse polarography is described and used to determine the solubility of DBDCB in water. The solubility of DBDCB in water calculated from five analyses is 0. 164% (standard deviation 0. 010%) for a 5-ms pulse time or 0. 158% (standard deviation 0. 004%) for a 50-ms pulse time.
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Doi:10.1021/ja00833a017
(1974)Doi:10.1007/BF00531500
(1993)Doi:10.1021/acs.chemmater.8b00393
(2018)Doi:10.1016/j.dyepig.2019.108000
(2020)Doi:10.1021/jp046604x
(2004)Doi:10.1021/jo01231a007
(1936)
