Tetrahedron Letters p. 8783 - 8786 (1998)
Update date:2022-08-04
Topics:
Angelini, Mark P.
Lee-Ruff, Edward
A photochemical glycosylation is described using the chiral cyclobutanone 1. Irradiation of ketone 1 in the presence of monosaccharides 2 and 3 gives photoadducts derived from OH insertion of the transient carbene. The carbene inserts into the N-H group in the case of nucleoside 4.
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