1576-92-7Relevant articles and documents
A novel photochemical synthesis of dideoxyfuranosyl disaccharides
Angelini, Mark P.,Lee-Ruff, Edward
, p. 8783 - 8786 (1998)
A photochemical glycosylation is described using the chiral cyclobutanone 1. Irradiation of ketone 1 in the presence of monosaccharides 2 and 3 gives photoadducts derived from OH insertion of the transient carbene. The carbene inserts into the N-H group in the case of nucleoside 4.
Lipase-catalyzed monoprotection of 1,4-diols in an organic solvent using vinyl benzoate as acyl transfer agent
Ciuffreda, Pierangela,Casati, Silvana,Santaniello, Enzo
, p. 3663 - 3665 (2007/10/03)
Lipase from Mucor miehei (MML) has been selected as the most suitable enzyme to catalyze the efficient monobenzoylation of 1,4-diols using vinyl benzoate as acyl transfer reagent in tert-butyl methyl ether. The regioselectivity of the monobenzoylation of
A novel approach toward the synthesis of chiral 2,3-dideoxy nucleosides and their carbocyclic analogues
Lee-Ruff,Wan,Jiang
, p. 2114 - 2118 (2007/10/02)
Photochemical ring-expansion of chiral 2(S),3(R)-bis [(benzoyloxy)methyl]cyclobutanone (3) in the presence of alcohols and acidic N-H functional groups gives anomeric mixtures of acetals and N-amino acetals, respectively, with retention of stereochemistry
