
Bulletin of the Chemical Society of Japan p. 1869 - 1870 (1983)
Update date:2022-08-10
Topics:
Hasegawa, Tadashi
Shimizu, Toshio
Iwasaki, Kazuhiko
Oguchi, Shoshichi
Irradiation of S-alkyl 3-oxobutanethioate (1) in benzene or ethanol yielded the disulfide 2.Irradiation of S-alkyl α-bromothioacetate also gave the disulfide 2.The photochemical reaction of the 3-oxobutanethioate 1 involves the Norrish Type I reaction followed by rapid fragmentation of the radical CH2COSR to the thiyl radical 5.
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Doi:10.1002/hlca.19830660716
(1983)Doi:10.1021/ie50544a038
(1955)Doi:10.1021/ja01284a023
(1937)Doi:10.1021/j100273a039
(1986)Doi:10.1039/b211645f
(2003)Doi:10.1021/cn4001236
(2013)