Journal of Organometallic Chemistry p. 169 - 175 (1981)
Update date:2022-08-16
Topics:
Huang, Yaozeng
Li, Jisen
Zhou, Jianqiang
Wang, Qiwen
Gui, Meimei
Oligomerization of perfluoropropylene catalyzed by four ?-bis(arene)chromium(0) complexes (arene = benzene, diphenyl, 1,3,5-trimethylbenzene and hexamethylbenzene) were compared.Besides dimers (I, II) and trimers (III, IV) reported previously <1>, two defluorotrimers VA and VB were found to be present in the oligomer mixtures.The formation of VA and VB was shown to be derived from trimer IV by hydrogenation followed by elimination of two moles of hydrogen fluoride.
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