Angewandte Chemie - International Edition p. 5830 - 5833 (2011)
Update date:2022-08-16
Topics:
Nakamula, Ikuse
Yamanoi, Yoshinori
Imaoka, Takane
Yamamoto, Kimihisa
Nishihara, Hiroshi
Mix and more than match: Relative to the catalytic activity of pure Rh nanoparticles in a dendrimer cage, Rh/Fe bimetallic nanoparticles in dendrimers have improved catalytic activity towards the hydrogenation of olefins, and unlike Wilkinson catalyst could catalyze nitroarene hydrogenation (see scheme, G4=4th generation dendrimer).
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