THE RADICAL COUPLING MECHANISM IN THE DIAZO COUPLING REACTION. MIGRATION VS. DECOMPOSITION OF PHENYLAZO RADICAL GENERATED FROM PHENYLAZO 1-NAPHTHYL ETHER IN THE SOLVENT CAGE

DOI: 10.1016/S0040-4039(00)99586-8

Source and publish data:

Tetrahedron Letters p. 1811 - 1814 (1989)

Update date:2022-08-16

Topics:

Authors:

Tezuka, Takahiro

Tanikawa, Hiroharu

Sasaki, Katsunori

Tajima, Harumi

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Article abstract of DOI:10.1016/S0040-4039(00)99586-8

The thermal reaction of phenylazo 1-naphthyl ether generates a pair of phenylazo and naphthoxy radicals in the solvent cage, in which these radicals couple together at the aromatic carbon to give 4-phenylazo-1-naphthol and 2-phenylazo-1-naphthol.

Full text of DOI:10.1016/S0040-4039(00)99586-8

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