Journal of the Chemical Society. Chemical communications p. 599 - 600 (1987)
Update date:2022-08-25
Topics:
Karlin, Kenneth D.
Cruse, Richard W.
Gultneh, Yilma
A hydroperoxo-dicopper(II) complex (3) can be prepared by (a) direct protonation of a peroxo-dicopper(II) complex (2), (b) oxygenation of a ligand-protonated form of the dicopper(I) precursor of (2), and (c) reaction of hydrogen peroxide with a hydroxo-bridged dicopper(II) complex (5); (3) reacts quantitatively with triphenylphosphine or tetrahydrothiophene to give (5) and oxygenated products.
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